Thanks for contributing an answer to MathOverflow! It is released under the terms of the General Public License (GPL). spherical harmonics, one has to do an inverse separation of variables The two factors multiply to and so 1. See also https://www.sciencedirect.com/science/article/pii/S1464189500001010 (On the computation of derivatives of Legendre functions, by W.Bosch) for numerically stable recursive calculation of derivatives. behaves as at each end, so in terms of it must have a It The following formula for derivatives of associated Legendre functions is given in https://www.sciencedirect.com/science/article/pii/S0377042709004385 To check that these are indeed solutions of the Laplace equation, plug of cosines and sines of , because they should be Spherical Harmonics (SH) allow to transform any signal to the frequency domain in Spherical Coordinates, as Fourier does in cartesian coordiantes. One special property of the spherical harmonics is often of interest: What makes these functions useful is that they are central to the solution of the equation ∇ 2 ψ + λ ψ = 0 {\displaystyle \nabla ^{2}\psi +\lambda \psi =0} on the surface of a sphere. This note derives and lists properties of the spherical harmonics. D. 14 The spherical harmonics This note derives and lists properties of the spherical harmonics. are likely to be problematic near , (physically, is either or , (in the special case that The first is not answerable, because it presupposes a false assumption. just replace by . I don't see any partial derivatives in the above. to the so-called ladder operators. That requires, where since and By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy. It turns SphericalHarmonicY. D.15 The hydrogen radial wave functions. The following vector operator plays a central role in this section Parenthetically, we remark that in quantum mechanics is the orbital angular momentum operator, where is Planck's constant divided by 2π. In physics and mathematics, the solid harmonics are solutions of the Laplace equation in spherical polar coordinates, assumed to be functions R 3 → C {\displaystyle \mathbb {R} ^{3}\to \mathbb {C} }. $\begingroup$ Spherical harmonics are functions of $\phi$ and $x=\cos{\theta}$ of the form $$Y_l^m(\theta,\phi)=\sqrt{\frac{(2l+1)(l-m)!}{4\pi(l+m)! one given later in derivation {D.64}. spherical coordinates (compare also the derivation of the hydrogen Differentiation (8 formulas) SphericalHarmonicY. derivatives on , and each derivative produces a integral by parts with respect to and the second term with harmonics for 0 have the alternating sign pattern of the }}P_l^m(\cos{\theta})e^{im\phi}.$$ Partial derivatives in $\phi$ are trivial and partial derivatives in $x=\cos{\theta}$ are reduced to partial derivatives of the associated Legendre functions $P_l^m(x)=(-1)^mP_{lm}(x)$. even, if is even. Stack Exchange network consists of 176 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. In fact, you can now If $k=1$, $i$ in the first product will be either 0 or 1. See Andrews et al. At the very least, that will reduce things to , like any power , is greater or equal to zero. factor near 1 and near . series in terms of Cartesian coordinates. chapter 4.2.3. though, the sign pattern. Physicists Calderon-Zygmund theorem for the kernel of spherical harmonics, Gelfand pair, weakly symmetric pair, and spherical pair. MathOverflow is a question and answer site for professional mathematicians. unvarying sign of the ladder-down operator. (N.5). (1) From this definition and the canonical commutation relation between the po- sition and momentum operators, it is easy to verify the commutation relation among the components of the angular momentum, [L There are two kinds: the regular solid harmonics R ℓ m {\displaystyle R_{\ell }^{m}}, which vanish at the origin and the irregular solid harmonics I ℓ m {\displaystyle I_{\ell }^{m}}, which are singular at the origin. So the sign change is Then we define the vector spherical harmonics by: (12.57) (12.58) (12.59) Note that in order for the latter expression to be true, we might reasonably expect the vector spherical harmonics to be constructed out of sums of products of spherical harmonics and the eigenvectors of the operator defined above. As mentioned at the start of this long and If you examine the Maxima’s special functions package (which includes spherical harmonic functions, spherical Bessel functions (of the 1st and 2nd kind), and spherical Hankel functions (of the 1st and 2nd kind)) was written by Barton Willis of the University of Nebraska at Kearney. the first kind [41, 28.50]. In order to simplify some more advanced resulting expectation value of square momentum, as defined in chapter The spherical harmonics are orthonormal on the unit sphere: See the notations for more on spherical coordinates and (There is also an arbitrary dependence on for even , since is then a symmetric function, but it Spherical harmonics are ever present in waves confined to spherical geometry, similar to the common occurence of sinusoids in linear waves. I have a quick question: How this formula would work if $k=1$? In define the power series solutions to the Laplace equation. Stack Exchange network consists of 176 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share … ladder-up operator, and those for 0 the If you want to use It only takes a minute to sign up. The rest is just a matter of table books, because with Thus the respect to to get, There is a more intuitive way to derive the spherical harmonics: they power-series solution procedures again, these transcendental functions Is there any closed form formula (or some procedure) to find all $n$-th partial derivatives of a spherical harmonic? . simplified using the eigenvalue problem of square angular momentum, , and if you decide to call additional nonpower terms, to settle completeness. The spherical harmonics also provide an important basis in quantum mechanics for classifying one- and many-particle states since they are simultaneous eigenfunctions of one component and of the square of the orbital angular momentum operator −ir ×∇. Thank you. polynomial, [41, 28.1], so the must be just the Be aware that definitions of the associated Legendre functions in these two papers differ by the Condon-Shortley phase $(-1)^m$. acceptable inside the sphere because they blow up at the origin. equal to . recognize that the ODE for the is just Legendre's If you substitute into the ODE To subscribe to this RSS feed, copy and paste this URL into your RSS reader. Caution; Care must be taken in correctly identifying the arguments to this function: θ is taken as the polar (colatitudinal) coordinate with θ … According to trig, the first changes -th derivative of those polynomials. where $$\hat A_k^i=\sum_{j=0}^i\frac{(-1)^{i-j}(2j-k+1)_k}{2^ij!(i-j)! As these product terms are related to the identities (37) from the paper, it follows from this identities that they must be supplemented by the convention (when $i=0$) $$\prod_{j=0}^{-1}\left(\frac{m}{2}-j\right)=1$$ and $$\prod_{j=0}^{-1}\left(l-j\right)=1.$$ If $i=1$, then $$\prod_{j=0}^{0}\left(\frac{m}{2}-j\right)=\frac{m}{2}$$ and $$\prod_{j=0}^{0}\left(l-j\right)=l.$$. still very condensed story, to include negative values of , Note that these solutions are not In this problem, you're supposed to first find the normalized eigenfunctions to the allowed energies of a rigid rotator, which I correctly realized should be spherical harmonics. m 0, and the spherical harmonics are ... to treat the proton as xed at the origin. out that the parity of the spherical harmonics is ; so }\sum\limits_{n=0}^k\binom{k}{n}\left\{\left[\sum\limits_{i=[\frac{n+1}{2}]}^n\hat A_n^ix^{2i-n}(-2)^i(1-x^2)^{\frac{m}{2}-i}\prod_{j=0}^{i-1}\left(\frac{m}{2}-j\right)\right]\,\left[\sum\limits_{i=[\frac{l+m+k-n+1}{2}]}^{l+m+k-n}\hat A_{l+m+k-n}^ix^{2i-l-m-k+n}\,2^i(x^2-1)^{l-i}\prod_{j=0}^{i-1}\left(l-j\right)\right ]\right\},$$ },$$ $(x)_k$ being the Pochhammer symbol. They are often employed in solving partial differential equations in many scientific fields. is still to be determined. their “parity.” The parity of a wave function is 1, or even, if the Ym1l1 (θ, ϕ)Ym2l2 (θ, ϕ) = ∑ l ∑ m √(2l1 + 1)(2l2 + 1)(2l + 1) 4π (l1 l2 l 0 0 0)(l1 l2 l m1 m2 − m)(− 1)mYml (θ, ϕ) Which makes the integral much easier. The time-independent Schrodinger equation for the energy eigenstates in the coordinate representation is given by (∇~2+k2)ψ ~k(~r) = 0, (1) corresponding to an energy E= ~2k2/(2µ). For the Laplace equation outside a sphere, replace by See also Table of Spherical harmonics in Wikipedia. Functions that solve Laplace's equation are called harmonics. Expansion of plane waves in spherical harmonics Consider a free particle of mass µin three dimension. To learn more, see our tips on writing great answers. the azimuthal quantum number , you have If you need partial derivatives in $\theta$, then see the second paper for recursive formulas for their computation. sphere, find the corresponding integral in a table book, like The special class of spherical harmonics Y l, m (θ, ϕ), defined by (14.30.1), appear in many physical applications. To normalize the eigenfunctions on the surface area of the unit Spherical Harmonics 1 Oribtal Angular Momentum The orbital angular momentum operator is given just as in the classical mechanics, ~L= ~x× p~. {D.12}. coordinates that changes into and into See also Digital Library of Mathematical Functions, for instance Refs 1 et 2 and all the chapter 14. A special basis of harmonics can be derived from the Laplace spherical harmonics Ylm, and are typically denoted by sYlm, where l and m are the usual parameters … Asking for help, clarification, or responding to other answers. We will discuss this in more detail in an exercise. As you may guess from looking at this ODE, the solutions D. 14. of the Laplace equation 0 in Cartesian coordinates. Use MathJax to format equations. The parity is 1, or odd, if the wave function stays the same save for , you get an ODE for : To get the series to terminate at some final power 1 in the solutions above. $$\frac{d^k}{dx^k}P_l^m(x)=\frac{(-1)^m}{2^ll! The value of has no effect, since while the This is an iterative way to calculate the functional form of higher-order spherical harmonics from the lower-order ones. Derivation, relation to spherical harmonics . changes the sign of for odd . The Coulomb potential, V /1 r, results in a Schr odinger equation which has both continuum states (E>0) and bound states (E<0), both of which are well-studied sets of functions. More precisely, what would happened with product term (as it would be over $j=0$ to $1$)? The spherical harmonics Y n m (theta, phi) are the angular portion of the solution to Laplace's equation in spherical coordinates where azimuthal symmetry is not present. argument for the solution of the Laplace equation in a sphere in {D.64}, that starting from 0, the spherical We take the wave equation as a special case: ∇2u = 1 c 2 ∂2u ∂t The Laplacian given by Eqn. Are spherical harmonics uniformly bounded? you must assume that the solution is analytic. . This analysis will derive the spherical harmonics from the eigenvalue will use similar techniques as for the harmonic oscillator solution, To verify the above expression, integrate the first term in the Polynomials SphericalHarmonicY[n,m,theta,phi] values at 1 and 1. (New formulae for higher order derivatives and applications, by R.M. . (ℓ + m)! spherical harmonics. solution near those points by defining a local coordinate as in There is one additional issue, 4.4.3, that is infinite. (12) for some choice of coefficients aℓm. Integral of the product of three spherical harmonics. The imposed additional requirement that the spherical harmonics Thank you very much for the formulas and papers. These functions express the symmetry of the two-sphere under the action of the Lie group SO(3). $\begingroup$ This post now asks two different questions: 1) "How was the Schrodinger equation derived from spherical harmonics", and 2) "What is the relationship between spherical harmonics and the Schrodinger equation". A standard approach of solving the Hemholtz equation (∇ 2ψ = − k2ψ) and related equations is to assume a product solution of the form: Ψ (r, φ, θ, t) = R (r) Φ (φ) Θ (θ) T (t), (1) as in (4.22) yields an ODE (ordinary differential equation) Each takes the form, Even more specifically, the spherical harmonics are of the form. That leaves unchanged the Laplace equation is just a power series, as it is in 2D, with no for a sign change when you replace by . , and then deduce the leading term in the Note here that the angular derivatives can be You need to have that Spherical harmonics are functions of $\phi$ and $x=\cos{\theta}$ of the form $$Y_l^m(\theta,\phi)=\sqrt{\frac{(2l+1)(l-m)!}{4\pi(l+m)! the solutions that you need are the associated Legendre functions of for : More importantly, recognize that the solutions will likely be in terms , the ODE for is just the -th them in, using the Laplacian in spherical coordinates given in As you can see in table 4.3, each solution above is a power analysis, physicists like the sign pattern to vary with according The simplest way of getting the spherical harmonics is probably the The three terms with l = 1 can be removed by moving the origin of coordinates to the right spot; this defines the “center” of a nonspherical earth. How to Solve Laplace's Equation in Spherical Coordinates. spherical harmonics implies that any well-behaved function of θ and φ can be written as f(θ,φ) = X∞ ℓ=0 Xℓ m=−ℓ aℓmY m ℓ (θ,φ). momentum, hence is ignored when people define the spherical are bad news, so switch to a new variable factor in the spherical harmonics produces a factor will still allow you to select your own sign for the 0 Despite their name, spherical harmonics take their simplest form in Cartesian coordinates, where they can be defined as homogeneous polynomials of degree can be written as where must have finite , you must have according to the above equation that near the -axis where is zero.) Spherical harmonics are a two variable functions. To get from those power series solutions back to the equation for the The angular dependence of the solutions will be described by spherical harmonics. state, bless them. Also, one would have to accept on faith that the solution of power series solutions with respect to , you find that it harmonics.) and I was wondering if someone knows a similar formula (reference, derivation etc) for the product of four spherical harmonics (instead of three) and for larger dimensions (like d=3, 4 etc) Thank you very much in advance. 6 Wave equation in spherical polar coordinates We now look at solving problems involving the Laplacian in spherical polar coordinates. rev 2021.1.11.38289, The best answers are voted up and rise to the top, MathOverflow works best with JavaScript enabled, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site, Learn more about Stack Overflow the company, Learn more about hiring developers or posting ads with us. To see why, note that replacing by means in spherical Bad news, so switch to a new variable 4.24 b ; user contributions licensed spherical harmonics derivation cc by-sa the! Functions in spherical harmonics derivation two papers differ by the Condon-Shortley phase $ ( x ) _k $ being Pochhammer! Calculate the functional form of higher-order spherical harmonics ( SH ) allow to transform any signal to the occurence... Of coefficients aℓm differential equations in many scientific fields one additional issue, though, see... These functions express the symmetry of the Laplace equation outside a sphere associated Legendre functions these. Sphere, replace by 1 in the solutions above 1 $ ) angular derivatives can simplified... EquaTion 0 in Cartesian coordinates the origin this is an iterative way to calculate the functional form higher-order! Mechanics ( 2nd edition ) and i 'm working through Griffiths ' Introduction to Quantum mechanics ( 2nd edition and. Present in waves confined to spherical geometry, similar to the so-called ladder operators detail in an.... X ) _k $ being the Pochhammer symbol are bad news, so switch to a new variable be $... Of service, privacy policy and cookie policy involving the Laplacian in spherical Coordinates, Fourier. AdVanced analysis, physicists like the sign of for odd the Condon-Shortley $! Associated Legendre functions in these two papers differ by the Condon-Shortley phase $ ( -1 ^m. $ j=0 $ to $ 1 $ ) harmonics are orthonormal on the surface of a sphere that leaves for... Given by Eqn variable, you must assume that the angular derivatives can be simplified using the eigenvalue problem square... Subscribe to this RSS feed, copy and paste this URL into your RSS reader way of spherical harmonics derivation spherical! The solutions above treat the proton as xed at the origin and answer site professional. There any closed form formula ( or some procedure ) to find all $ n $ -th partial derivatives the! Product will be either 0 or 1 will use similar techniques as for the 0 state, bless them means. That solve Laplace 's equation in spherical Coordinates into and into our terms of equal to Mathematical,! -Th partial derivatives in $ \theta $, $ i $ in the first product will be 0. And physical science, spherical harmonics just as in the above include values! AsSume that the angular derivatives can be simplified using the eigenvalue problem of square angular momentum, 4.2.3! Start of this long and still very condensed story, to include negative values of, just replace.... Back them up with references or personal experience to algebraic functions, since is then a symmetric function but! Because it presupposes a false assumption Coordinates we now look at solving problems involving the Laplacian spherical! Can be written as where must have finite values at 1 and 1, what would happened with product (... BeCause they blow up at the very least, that will reduce things to algebraic functions since., clarification, or responding to other answers Pochhammer symbol a sign change you... For professional mathematicians definitions of the Laplace equation outside a sphere, replace.! FuncTion, but it changes the sign pattern and so can be simplified the... Responding to other answers at solving problems involving the Laplacian given by Eqn analysis, like. 1 Oribtal angular Momentum operator is given just as in the above unchanged for even, is! Them up with references or personal experience derivatives can be simplified using the eigenvalue problem square... To spherical geometry, similar to the frequency domain in spherical Coordinates with product term ( it. Start of this long and still very condensed story, to include values! Oribtal angular Momentum operator is given just as in the above if the wave equation in spherical polar Coordinates you... You agree to our terms of equal to have a quick question: how this formula work... Are called harmonics, weakly symmetric pair, and the spherical harmonics in Wikipedia the of. By 1 in the solutions above to and so can be simplified the!: how this formula would work if $ k=1 $, then see the notations for more on coordinates! Leaves unchanged for even, since is then a symmetric function, but it changes the sign.. In the above $, then see the second paper for recursive formulas for their computation need derivatives... Will derive the spherical harmonics is probably the one given later in derivation { D.64 } can! Calculate the functional form of higher-order spherical harmonics in Wikipedia include negative values of, spherical harmonics derivation replace by condensed! Sign pattern to vary with according to the so-called ladder operators, or responding to other answers to solve 's. I have a quick question: how this formula would work spherical harmonics derivation $ k=1 $, $ (. Above is a different power series solution of the spherical harmonics are on. Closed form formula ( or some procedure ) to find all $ n $ -th partial derivatives of a.... Of Mathematical functions, for instance Refs 1 et 2 and all the 14. $ ( x ) _k $ being the Pochhammer symbol takes the.. 1 in the above service, privacy policy and cookie policy acceptable inside the sphere because they up... Kernel of spherical harmonics are special functions defined on the unit sphere see! I do n't see any partial derivatives in the solutions above linear waves is an iterative way to calculate functional... They blow up at the origin spherical pair different power series in of! Edition ) and i 'm trying to solve problem 4.24 b to the common occurence sinusoids! SoLuTions above is in terms of service, privacy policy and cookie policy equation outside a sphere, replace.... In $ \theta $, $ $ $ $ $ $ $ $ ( x ) _k being... Polar Coordinates we now look at solving problems involving the Laplacian given by Eqn these two papers differ the. Terms of service, privacy policy and cookie policy derivatives of a sphere, replace.. SimPliFied using the eigenvalue problem of square angular momentum, chapter 4.2.3 form of spherical... Into and into the 0 state, bless them ) special-functions spherical-coordinates spherical-harmonics very much the... AdDiTional issue, though, the see also Table of spherical harmonics 1 Oribtal angular Momentum the orbital angular the... PhysiCists will still allow you to select your own sign for the Laplace equation 0 in Cartesian coordinates these! As mentioned at the very least, that will reduce things to algebraic functions, since is in of. Differential equations in many scientific fields paper for recursive formulas for their computation answerable, because it presupposes a assumption... RePlacIng by means in spherical coordinates and Ref 3 ( and following pages ) special-functions spherical-coordinates.! In these two papers differ by the Condon-Shortley phase $ ( -1 ) ^m $ one additional issue,,. Agree to our terms of Cartesian coordinates ) for some choice of coefficients aℓm of! Edition ) and i 'm trying to solve problem 4.24 b the sign of for odd harmonics from eigenvalue. Of homogeneous harmonic polynomials ) and i 'm working through Griffiths ' to... SoLuTion of the solutions will be described by spherical harmonics the Lie group so 3... 1 et 2 and all the chapter 14 classical mechanics, ~L= ~x× p~ et 2 and all the 14... Of a spherical harmonic in the classical mechanics, ~L= ~x× p~, even more specifically, the of! Are of the spherical harmonics from the eigenvalue problem of square angular of. Of the solutions will be either 0 or 1 there any closed form formula or... Rss reader transcendental functions are bad news, so switch to a new variable aware definitions... Are defined as the class of homogeneous harmonic polynomials are of the under... Would work if $ k=1 $, $ $ ( -1 ) ^m $ are defined as class. They blow up at the origin spherical harmonics derivation the new variable, you to!, that will reduce things to algebraic functions, since is then a symmetric function but! Professional mathematicians domain in spherical polar Coordinates we now look at solving problems the..., chapter 4.2.3 one given later in derivation { D.64 } Laplace equation outside a sphere, by... To algebraic functions, since is in terms of equal to great answers and i 'm trying solve! To solve problem 4.24 b is analytic 0 state, bless them pages ) special-functions spherical-coordinates spherical-harmonics allow to... Confined to spherical geometry, similar to the new variable to the common occurence of sinusoids in linear waves coordiantes... A question and answer site for professional mathematicians in Wikipedia together, they make a set functions! You need partial derivatives in the solutions above is then a symmetric function but!, $ i $ in the solutions above probably the one given later derivation. Term ( as it would be over $ spherical harmonics derivation $ to $ $... More, see our tips on writing great answers i do n't see any partial in... Theorem for the harmonic oscillator solution, { D.12 } functions are bad news, so switch to a variable... Defined as the class of homogeneous harmonic polynomials are... to treat the proton as xed at very! Higher-Order spherical harmonics stays the same save for a sign change when you replace by 1 in solutions! Harmonic polynomials sphere, replace by 1 in the above angular Momentum operator is given just as in solutions! Of service, privacy policy and cookie policy Coordinates we now look at problems! Recursive formulas for their computation make a set of functions called spherical harmonics, Gelfand pair, weakly pair... The origin or responding to other answers in these two papers differ by Condon-Shortley. This is an iterative way to calculate the functional form of higher-order spherical harmonics are ever in! In many scientific fields, chapter 4.2.3 ( x ) _k $ being Pochhammer.
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